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Page 39

Data:

Solution BP(oC) ΔBP(oC) FP(oC) ΔFP(oC)
H2O 98.5 XXXXX 0 XXXXX
C6H12O6 102.0 3.50 -2.00 2.00
KNO3 100.5 2.00 -3.50 3.50

Analysis:

Solution avg Molality(m) avg experimental molar mass(g/mol) actual molar mass(g/mol) avg percent error(%)
H2O xxxxx xxxxx xxxxx xxxxx
C6H12O6 3.94 107 180.156 40.6
KNO3 1.45 104 101.11 2.97

KNO3:

Boiling:

m=2.00/(2*0.512)

m=1.94m *(50/1000)=0.097 mol

10/0.097= 103 g/mol

Freezing:

m=3.50/(2*1.85) =0.950m *(50/1000) =0.0475 mol

5/0.0475=105 g/mol

C6H12O6:

Boiling:

m=3.50/0.515 =6.80m *(50/1000)=0.34 mol

10/0.34=29.4 g/mol

Freezing:

m=2.00/1.85 = 1.08m 8(50/1000)=0.054 mol

10/0.054=185 g/mol

% error:

KNO3:

Boiling:

|103-101|/101 *100%=1.98% error

Freezing:

|105-101|/101 *100%=3.98% error

C6H12O6:

Boiling:

|29.4-180|/180 *100%=83.7% error

Freezing:

|185-180|/180 *100%=2.78% error