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Page 35

8. Rinse and dry the temperature probe, cup, and stirring rod. Dispose of the solution as directed.

9. Repeat steps 4-8, using 100.0mL of 0.5M hydrochloric acid instead of water. Use the same amount of NaOH.

10. Repeat steps 4-8, instead using 50.0mL of 1.0M HCl, and using 50.0mL of 1.0M NaOH.

Observations:

Combining the water and NaOH creates some bubbles. Combining 1.0M HCl and NaOH turns a litle pink.

Data:


Reaction 1
Reaction 2
Reaction 3
Mass NaOH
2.00g
2.00g
 
Mass Total
102g 102g 100g
Final Temperature
25.073 oC
31.593 oC
27.357 oC
Initial Temperature
20.675 oC
20.622 oC
20.504 oC
Change in Temperature
4.397 oC
10.972 oC
6.853 oC

Calculations:

MassR1= R1=100mL*1.00g/mol=100g +2.00g = 102g

MassR2= 100mL*1.00g/mol=100g +2.00g = 102g

Mass R2= 100mL*1.00g/mol=100g +2.00g R3= 102g

Mass R3= 50mL*1.00g/mol=50g *2=100g

 

q R1=R1= 4.18*102*4.397  q R1==1875J /1000=1.875kJ

q R2=R2= 4.18*102*10.972  q R2==4678J /1000=4.678kJ

q R3=R3=4.18*100*6.853  q R3==2865J /1000=2.865kJ

ΔH=-q       q=-ΔH