# Page 35

8\. Rinse and dry the temperature probe, cup, and stirring rod. Dispose of the solution as directed.

9\. Repeat steps 4-8, using 100.0mL of 0.5M hydrochloric acid instead of water. Use the same amount of NaOH.

10\. Repeat steps 4-8, instead using 50.0mL of 1.0M HCl, and using 50.0mL of 1.0M NaOH.

Observations:

Combining the water and NaOH creates some bubbles. Combining 1.0M HCl and NaOH turns a litle pink.

Data:

<table border="1" id="bkmrk-reaction-1-reaction-" style="border-collapse: collapse; width: 100%; height: 177.6px;"><colgroup><col style="width: 25%;"></col><col style="width: 25%;"></col><col style="width: 25%;"></col><col style="width: 25%;"></col></colgroup><thead><tr style="height: 29.6px;"><td style="height: 29.6px;">  
</td><td style="height: 29.6px;">Reaction 1  
</td><td style="height: 29.6px;">Reaction 2  
</td><td style="height: 29.6px;">Reaction 3  
</td></tr></thead><tbody><tr style="height: 29.6px;"><td style="height: 29.6px;">Mass NaOH  
</td><td style="height: 29.6px;">2.00g  
</td><td style="height: 29.6px;">2.00g  
</td><td style="height: 29.6px;"> </td></tr><tr style="height: 29.6px;"><td style="height: 29.6px;">Mass Total  
</td><td style="height: 29.6px;">102g</td><td style="height: 29.6px;">102g</td><td style="height: 29.6px;">100g</td></tr><tr style="height: 29.6px;"><td style="height: 29.6px;">Final Temperature  
</td><td style="height: 29.6px;">25.073 <sup>o</sup>C  
</td><td style="height: 29.6px;">31.593 <sup>o</sup>C  
</td><td style="height: 29.6px;">27.357 <sup>o</sup>C  
</td></tr><tr style="height: 29.6px;"><td style="height: 29.6px;">Initial Temperature  
</td><td style="height: 29.6px;">20.675 <sup>o</sup>C  
</td><td style="height: 29.6px;">20.622 <sup>o</sup>C  
</td><td style="height: 29.6px;">20.504 <sup>o</sup>C  
</td></tr><tr style="height: 29.6px;"><td style="height: 29.6px;">Change in Temperature  
</td><td style="height: 29.6px;">4.397 <sup>o</sup>C  
</td><td style="height: 29.6px;">10.972 <sup>o</sup>C  
</td><td style="height: 29.6px;">6.853 <sup>o</sup>C  
</td></tr></tbody></table>

Calculations:

Mass<sub>R1</sub>= 100mL\*1.00g/mol=100g +2.00g = <span style="text-decoration: underline;">102</span>g

Mass<sub>R2</sub>= 100mL\*1.00g/mol=100g +2.00g = <span style="text-decoration: underline;">102g</span>

Mass<sub>R3</sub>= 50mL\*1.00g/mol=50g \*2=<span style="text-decoration: underline;">100g</span>

q<sub>R1</sub>= 4.18\*102\*4.397 =1875J /1000=<span style="text-decoration: underline;">1.875kJ</span>

q<sub>R2</sub>= 4.18\*102\*10.972 =4678J /1000=<span style="text-decoration: underline;">4.678kJ</span>

q<sub>R3</sub>=4.18\*100\*6.853 =2865J /1000=<span style="text-decoration: underline;">2.865kJ</span>

ΔH=-q q=-ΔH